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Artifical Ground Freezing – For Environmental Remediation Printable Version Print Artifical Groundfreezing Project
Artificial ground freezing, a technique which has been used extensively for groundwater control and excavation support in the underground construction industry for over one hundred years, has recently been used for environmental applications. The versatility of this process and the advent of more powerful and energy-efficient refrigeration equipment provides a promising technology which has now been demonstrated and made readily available. While the primary concept of converting soil pore water to ice is relatively simple, its applications to remediation projects requires the complex integration of the thermal, structural and hydraulic properties of the soil as well as the construction know-how and specialized equipment.
Artificial ground freezing, as it is used today, was originally developed by F.H. Poetsch in 1883. Poetsch's process involves the circulation of a refrigerated coolant through a series of subsurface pipes to extract heat, thus converting the soil water to ice, creating a strong, watertight material. The material is so strong in fact, that it is routinely used as the only method of groundwater control and soil support for the construction of shafts, hundreds of feet into water-bearing soils.

Most ground freezing systems are quite similar in principle, with subtle differences in the engineering aspects of the individual sites. It is these differences which have been addressed and reported in the literature, and learned (in some cases the hard way)
Artificial ground freezing groundwater control and soil support
Figure 1. Typical scenario of freeze pipe spacing and indication which can be connected to a portable refrigeration plant, or liquid nitrogen tanker.
through extensive field experience. The single most important component of a ground freezing system is the subsurface refrigeration system, consisting of a series of refrigeration pipes, installed with various drilling techniques. The quantity, spacing, depth and size of the refrigeration pipes are unique to each site, and determined on the basis of the thermal and hydraulic properties of soils, construction schedules and cost effectiveness.

Within each of the freeze pipes, a smaller diameter feed pipe is installed permitting the downward circulation of the cooling medium which then flows to the surface through the annulus of the larger pipe. The cooling medium varies depending on the required application. Where very rapid freezing is required for applications such as containment after a spill, liquid nitrogen is used with temperatures well below -I50o C. For most applications however, a secondary coolant such as calcium chloride (brine) or ethylene glycol is used. This secondary coolant is chilled using large portable refrigeration plants which employ ammonia as a primary refrigerant. These refrigeration plants are typically mounted on conventional over-the-road trailers and are electrically powered using commercially available electricity or by diesel generators.

Once the system has been drilled and installed, it operates continuously as a closed system requiring constant monitoring with occasional plant adjustment and coolant flow modifications. After the initial freezing has been completed and the frozen barrier in place, the required refrigeration capacity is significantly reduced to maintain the frozen barrier.
Barrier Walls

Frozen earth barriers are designed and built to prevent the migration of contaminated groundwater. The frozen earth barrier can be used to contain the contamination during remediation activities on a temporary basis or can be installed for long-term use. For the purpose of this discussion, it is assumed that no excavation will be required, eliminating the need for structural considerations. The actual geometry of the barrier wall is extremely flexible, permitting locations near existing structures, utilities and right-of-ways. Successful construction applications using a frozen barrier to provide watertight excavations when subjected to over 20,000 pounds per square foot of hydrostatic pressure proves in no uncertain terms that the frozen earth is impermeable.

The preliminary design of barrier walls must consider the subsurface soil properties, time requirements, and cost factors related to both items. Each item is discussed in greater detail to identify how it relates to the design of the ground freezing system.
Subsuface Soil Properties

Most environmental projects in the remediation phase have considerably more subsurface investigation and characterization than conventional construction freezing projects which sometimes have nothing more than one sampled boring. As a minimum, the following information should be provided in the geologic report:
    1.  Identification of all soil strata;
    2.  Identification of contaminants and respective concentrations;
    3.  Index properties of soils including unfrozen water contents and grain size distribution;
    4.  Permeabilities of subsurface strata from field tests; and
    5.  Seasonal ground water levels.
The surface location and installation of the freeze pipes is based predominately on the geometry of the zone requiring isolation. The spacing between two adjacent refrigeration pipes and the depth of each pipe however, is dependent on the subsurface soil properties and groundwater conditions.

Soil strata identification is critical in determining the required depth of the frozen earth wall. In about half of the applications reviewed thus far, the barrier wall can be extended into a low permeability soil or rock, preventing vertical migration of the contaminant. In the remaining applications, angled, horizontal or directional drilling techniques are required to install the refrigeration pipes in a manner to isolate the bottom of the containment area. High permeability strata must also be identified as they can have a negative impact on the freezing process if not identified in the conceptual design stages.

Groundwater flow through permeable strata can retard and in some cases prevent the formation of the frozen barrier. In most applications however, it is possible to overcome the adverse effects of moving groundwater by either lowering the temperature of the refrigeration medium or reducing the spacing between the adjacent refrigeration pipes. Other subsurface properties, particularly the seasonal groundwater levels and permeability of soils must be considered in the evaluation of moving groundwater and are discussed later.

The type and concentrations of the contaminants are usually identified in the early phases of the investigation and are key factors in the design, long-term performance and construction of the frozen earth barrier. During the design phase, it is imperative that laboratory tests be conducted to determine the freeze point temperature. Undisturbed, contaminated samples should be retrieved from areas as close to the actual location of the proposed frozen earth wall as feasibly possible. This freeze point is used in the design phase to determine the required coolant temperature.

There are basically two situations that are frequently observed in designing ground freezing systems in contaminated soil. One situation is that in which the freeze pipes are installed in the contaminated soil and results of the freeze point laboratory tests are used to determine freeze temperatures. In this example there is a high level of confidence that once frozen, the wall will remain frozen and impermeable since it takes considerably more energy to form the wall initially than it does to maintain the wall in the frozen state

However, another situation which requires consideration is that in which the frozen earth wall is installed and formed in clean, uncontaminated soil, but at a later date will come in contact with the contaminated groundwater. In order to ensure that this contact will not erode or melt the frozen wall, rendering it unsuitable, laboratory investigations are required. The most accurate method in evaluating this situation is through a testing program which includes frozen soil permeability tests.
Groundfreezing Formation of frozen earth barrier
Figure 2. Formation of frozen earth barrier develops at different rates depending on the thermal and hydraulic properties of each stratum. Typically, rock and coarsegrained soils freeze faster than clays and silts.
In a frozen soil permeability test, an undisturbed sample of each soil stratum is frozen in a triaxial cell in which the cell fluid is ethylene glycol refrigerated to a temperature consistent with the outer fringe of the frozen earth wall. The permeate in this test should be the strongest concentration of contaminated groundwater that is expected in the field.

The back pressure on the sample as well as the head pressure on the permeate should be as close to field conditions as possible. This test should be conducted in a long-term mode, with careful measurements being recorded frequently. If it appears that the frozen material has failed, then it will be necessary to start with
a fresh sample and conduct the test at a colder temperature. Subsequent tests should be conducted at increasingly colder temperatures until a satisfactory test is completed.

The index properties of the soils, particularly the water content and grain-size analyses are needed to conduct thermal analysis. This analysis is used to determine the required time to freeze and also to assist in determining the spacing between refrigeration pipes. Typically the larger grained cohesionless sands and gravels freeze much quicker than the fine-grained clays and silts. For each soil type, thermal properties vary depending on the water content. Energy is required for the phase change from water to ice, therefore, the higher water content, the more energy or longer duration required to freeze. The majority of ground freezing projects conducted since the early 1900's have been in the construction industry and require refrigeration pipe spacing at an approximately 3.5-foot spacing, with an average coolant temperature of – 25oC.

As previously discussed, the potential for moving water must be carefully evaluated prior to the initiation of freezing procedures. Evaluation of the permeabilities should be completed using in-situ slug or pumping tests. Following this evaluation, piezometric levels should be verified across the entire area to be contained. Any observed gradients should be correlated with permeability values in order to evaluate groundwater velocities. These velocities are then used to determine the refrigeration pipe spacing and required coolant temperatures. Care should be taken when evaluating the piezometric levels that seasonal and / or tidal fluctuations are accounted for, as they can induce groundwater movement which can be detrimental to the freezing process.
Thermal Analysis

The thermal analysis is the most important component of designing the ground freezing system, during the construction of frozen earth barrier walls. Four independent parameters comprise the factors in completing the thermal analysis, assuming hydrostatic conditions are relatively static. Moving groundwater conditions are discussed in a subsequent section.

The four parameters are:
  • Thermal properties of the soil;
  • Required time to freeze;
  • Coolant temperatures; and
  • Freeze pipe spacing
The thermal properties of the soil are the single constant parameter of the analysis. Analysis may begin once this determination has been completed. The required parameters and typical values for both a sand and clay are presented in Table 1.
TABLE 1
Parameter Water
Content (%)
Unit Clay Value Sand Value
Unfrozen Conductivity 25 BTU/ft. hr. oF 0.92 1.2
Unfrozen Conductivity 25 BTU/ft. hr. oF 0.92 1.2
Frozen Conductivity 25 BTU/ft. hr. oF 1.1 1.0
Unfrozen Specific Heat 25 BTU/ft3. hr. oF 41.5 41.5
Frozen Specific Heat 25 BTU / ft3. hr. oF 29.3 29.3
Latent Heat 25 BTU / ft3. 3600 3600
Engineering Design

The thermal properties comprise the most constant parameter in this phase of the analysis, while the required time to freeze is the most variable and dependent on the other three. With the soil parameters remaining constant, it can be generally assumed that the warmer the coolant and the greater the spacing between freeze pipes, the longer it will take to freeze.
The coolant temperatures are a function of the refrigeration system capacity. There are two basic types of refrigeration plants used for frozen barrier construction. The single phase screw compressor capable of generating coolant temperatures to approximately -35oC and the two-phase machines capable of generating temperatures to -70oC. The electric energy required to produce these temperatures increases with the colder temperatures.

Each individual refrigeration plant is limited to the total linear footage of freeze pipes it can efficiently cool. For the single phase screw compressors, experience has shown that they can freeze between 7,000 to 10,500 feet of freeze pipe. As the footage increases, the maximum
Layne Christensen Artifical Ground Freezing
  Figure 3. Finite element model grid of a section of shaft prior to freezing.
coolant temperatures are higher during the initial freeze. As previously noted, the warmer temperatures will require a longer time to freeze.

The spacing between adjacent freeze pipes also effects the required time to freeze, but constant refrigeration capacity must be optimized. Greater spacing, results in less pipes, which results in cooler brine requirements. Tighter spacing requires more pipes, but the coolant will be warmer. Since installation costs are significant when adding pipes,generally the designer will use the greatest spacing possible to form the freeze with the required time frame.
Artifical Ground Freezing Hydraulic Analysis and Thermal Analysis Figure 3. Finite element model
grid of a section of shaft prior
to freezing.
The method of thermal analyses routinely used by the author involves a time-dependent heat transfer finite element system. The particular program used has water-to-ice phase change capabilities and has been used in over 30 construction applications. Three or four different models are used by the designer to estimate the temperature regime throughout the wall at any given time. For each model, the required time to freeze is computed by assuming constant coolant temperatures. The results are used to evaluate the time required freeze duration for each spacing.

After determining the spacing and corresponding number of pipes, the refrigeration capacity is computed. This process is based on a system of several trials, which are then evaluated in a cost comparison analysis.
Hydraulic Analysis

The thermal analysis was based on the assumption that the groundwater was essentially static. Groundwater velocities of less than 5 meters/day generally do not have a significant impact on the freezing process. When velocities are greater than 5 meters/day, design adjustments must be made, either by lowering the coolant temperature or decreasing the spacing between two adjacent freeze pipes. Increasing the required time to freeze will not compensate for moving groundwater.
Installation Procedures

The most significant aspect of the construction of a frozen earth barrier wall is the drilling and placement of each individual freeze pipe. The pipes must not only be installed quickly, but within close tolerance to the vertical. Pipes installed with 3.5-foot spacings on center could have considerably greater spacings at depth if there is no alignment control during drilling.

During the drilling, it is necessary to keep the borehole open throughout the entire depth until the freeze pipe is lowered. Several methods of drilling have been used including hollow stem augers, mud rotary and variations on the casing advancer system. A newer method which was recently used on a deep shaft construction project in New York City is the reverse rotary dual tube method. This system is capable of advancing the drill bit at rates of up to 100 feet per hour in glacially deposited subsoils. After the initial borehole is drilled, a slightly larger diameter borehole casing is then drilled permitting the retraction of the bit while keeping the hole open. The freeze pipe is then lowered into the cased hole by welding threaded 20 to 40 foot sections. After the pipe is lowered, the casing is removed and each individual freeze pipe is pressure tested for leaks and surveyed for verticality using an orientable inclinometer. Should any two pipes have large deviations exceeding allowable tolerances, an additional pipe is installed.

After completion of the drilling and pipe installation, the system is connected to the refrigeration plant via a supply and return manifold consisting of 6-inch diameter pipes located around the perimeter of the barrier wall. After the pipes have been connected, the entire system is charged with the circulating coolant, either calcium chloride or environmentally safe ethylene glycol. This coolant is chilled via the refrigerant plant and circulated through the manifold system and corresponding freeze pipes. The circulation is maintained by a series of centrifugal pumps located at the refrigeration plant and within the manifold system, if required.

A key point often overlooked in the operation of ground freezing systems, is that the coolant serves as a heat transfer medium, extracting the heat from the ground as it circulates through the pipes. The volume and rate of coolant flow through the entire system, including the refrigeration plant, is equally as critical to the freezing process as the temperature. A computer simulation of the coolant hydraulics, much like that used for network pipe analysis is often used to check coolant velocities on those projects that have unusually long supply and return manifolds.
Instrumentation

Once the freezing process has begun, careful monitoring is required to ensure formation of the barrier wall and also to verify when freezing is complete. The most direct method of evaluating the frozen barrier formation is ground temperature measurement. During the drilling process, several temperature monitoring pipes are installed. These pipes are identical to the freeze pipes, except they are not connected to the coolant circulation system. Instead, they are filled with calcium chloride to prevent freezing while a series of thermocouple sensors are lowered into the pipes. The thermocouples are placed at specific depths within each pipe to correspond to the various subsurface strata.

The coolant flow, temperature and pressure are monitored at various locations throughout the manifold to verify the results of the hydraulic network analysis. Quite often it is necessary to make adjustments to various flow valves to balance hydraulics thus ensuring the uniform formation of the barrier wall. In some cases where there are measurable flow deficiencies, it is necessary to install additional pumps within the system.

During the freezing, continuous monitoring of the refrigeration plant(s) is also required. The more modern refrigeration plants used for ground freezing are electrically driven trailer-mounted mobile units. Ammonia is used as the primary refrigerant which chills the calcium chloride or ethylene glycol in a large heat exchanger. Most plants require 480 volts, three phase electrical power which is available using commercial electricity or diesel driven generators. Monitoring of plant amperage, refrigerant pressures and process temperatures is required several times each day. The data are evaluated and compared to the ground temperature response to verify that the system is operating in accordance with the design.
Completion

Complete formation of the frozen earth wall is usually indicated by the ground temperature data, and confirmed by piezometric levels. In construction applications, a pump test is usually conducted within the contained one. External piezometers are measured and their failure to reflect the pumping operations confirms the integrity of the barrier. Once this formation is confirmed, the plant operation and corresponding electric power is significantly reduced. For frozen walls without a side exposed to the air as in a construction excavation, the maintenance may only require the plant to run two or three days every three weeks. In Milwaukee, Wisconsin, there have been several instances where frozen ground for deep shaft construction has remained frozen well over one year after the freezing has been terminated.
Application II Solidification

In certain remediation activities, the removal of contaminated soils can be more easily accomplished when solidified. Solidification can not only facilitate the removal process, but it can greatly reduce the volatilization of components and eliminate hazardous vapors. The basic design and installation procedures are similar to those used on the barrier walls with the exception of the thermal analysis.

When using freezing to solidify a contaminated area, the thermal finite element method model is a critical tool to determine the required placement and spacing of the freeze pipes. The solidification process has been used recently in conjunction with a deep shaft excavation. Ground freezing was selected as the excavation support system for constructing several shafts on a tunnel construction project. Prior to the shaft excavation, a sludge like material was encountered in the shaft vicinity at a depth of approximately IS feet. Four sampled borings were conducted to retrieve samples for analytical testing. Results of the laboratory tests are presented in Table A-1 attached in the Appendix.

The consistency of the sludge material and the foul odors prompted concern from the general contractor. The high levels of lead and reactive sulfides made disposal of the excavated material much more difficult than conventional excavation. Solidification using artificial freezing was selected as the method to expedite the sludge removal and to reduce the potential of volatilization during excavation of the shaft. Initial plans called for complete freezing during the late fall with removal during the winter, thus taking advantage of the colder temperatures to keep the waste solid after excavation. Once excavated, the soil would be stored on site while analytical testing would be conducted.

Design modifications to the original freezing system were required to ensure that solidification could be completed within the contractor's required time frame. Finite element thermal analyses were completed and indicated that in order to minimize the need for addition freeze pipes, coolant temperatures of at least – 31oC would be required. Modifications were made to the refrigeration plant which resulted in the production of the much colder calcium chloride.

The freezing period lasted approximately 8 weeks, with ground temperature measurements taken daily. This particular project had considerably less total freeze pipe footage than the maximum capacity afforded by the refrigeration plant. The cooler weather increased the efficiency of the refrigeration system, producing brine coolant temperatures of approximately – 32oC.

Excavation was initiated using pneumatically powered spades which fractured the frozen waste into small pieces ranging from 4 to 12 inches in average diameter. After spading, the fractured waste was removed from the excavation using a crane-mounted excavation bucket.
The frozen ground concurrently served as a groundwater barrier and excavation support system. Excavation proceeded on a 24 hour basis and lasted approximately 21/2 weeks. During this time, constant air quality monitoring was conducted. Monitoring included organic vapors, methane, oxygen content and explosive potential. During the early phases of the excavation, the organic vapor analyzer indicated extremely high levels of organic vapor. These levels were the maximum detectable by the OVA, thus requiring the suspension of removal activities pending laboratory analysis.

Groundfreezing groundwater barrier and excavation support system
Figure 5. Schematic of the ground freezing
system used for remediation of contaminated soils.
The excavation level at this point was approximately five to eight feet above the zone that boring information had indicated the presence of contaminated soils. The laboratory analysis of these soils found no detectable levels of any contaminant. Further investigation revealed that gas used to prevent the air hammers from freezing was causing the OVA to show the abnormally high levels of organic gases.
After this discovery, OVA readings were taken periodically, after the air equipment was briefly removed from the excavation. This periodic monitoring permitted the anti-freeze gas to evacuate and virtually eliminated any indications of the presence of organic vapors. The high levels of reactive sulfides in the boring samples caused concern related to the presence of hydrogen sulphide gas within the excavation. At no time during the excavation of the frozen material were any concentrations of this gas detected.

As the excavation progressed, samples were collected with a frequency of approximately one sample for each foot of excavated soil. An interesting perspective related to the nature of soils occurred during the sampling process. While the majority of the material collected and placed in the sample jars appeared like a clayey soil material upon removal from the excavation, it rapidly melted to a sludge like material when the sample jars were transferred into the project engineers trailer prior to shipment to the laboratory. This confirmed the engineers assumption that it would be necessary to keep the material frozen until it could be transferred to a special waste landfall.

Excavation through the frozen sludge material progressed rapidly as crews worked continuous 24-hour shifts. Visual observation of the excavation clearly indicated when the extent of the frozen sludge had been reached. The excavated material was temporarily stored on site, then transferred to a special waste landfall. Excavation proceeded continuously into the clean soils without any significant changes in procedure except for the elimination of the health and safety program and continuous sampling. Excavated soils from the remainder of the shaft were used as fill for various earthwork projects.
Conclusion

The frozen ground concurrently served as a groundwater barrier and excavation support system. Excavation proceeded on a 24 hour basis and lasted approximately 21/2 weeks. During this time, constant air quality monitoring was conducted. Monitoring included organic vapors, methane, oxygen content and explosive potential. During the early phases of the excavation, the organic vapor analyzer indicated extremely high levels of organic vapor. These levels were the maximum detectable by the OVA, thus requiring the suspension of removal activities pending laboratory analysis.

The excavation level at this point was approximately five to eight feet above the zone that boring information had indicated the presence of contaminated soils. The laboratory analysis of these soils found no detectable levels of any contaminant. Further investigation revealed that gas used to prevent the air hammers from freezing was causing the OVA to show the abnormally high levels of organic gases.

After this discovery, OVA readings were taken periodically, after the air equipment was briefly removed from the excavation. This periodic monitoring permitted the anti-freeze gas to evacuate and virtually eliminated any indications of the presence of organic vapors. The high levels of reactive sulfides in the boring samples caused concern related to the presence of hydrogen sulphide gas within the excavation. At no time during the excavation of the frozen material were any concentrations of this gas detected.

As the excavation progressed, samples were collected with a frequency of approximately one sample for each foot of excavated soil. An interesting perspective related to the nature of soils occurred during the sampling process. While the majority of the material collected and placed in the sample jars appeared like a clayey soil material upon removal from the excavation, it rapidly melted to a sludge like material when the sample jars were transferred into the project engineers trailer prior to shipment to the laboratory. This confirmed the engineers assumption that it would be necessary to keep the material frozen until it could be transferred to a special waste landfall.

Excavation through the frozen sludge material progressed rapidly as crews worked continuous 24-hour shifts. Visual observation of the excavation clearly indicated when the extent of the frozen sludge had been reached. The excavated material was temporarily stored on site, then transferred to a special waste landfall. Excavation proceeded continuously into the clean soils without any significant changes in procedure except for the elimination of the health and safety program and continuous sampling. Excavated soils from the remainder of the shaft were used as fill for various earthwork projects.

The case study briefly described in this paper demonstrates how the innovative use of this readily available technology has been used successfully for environmental remediation. Additional applications on other projects throughout the country are currently being considered, and offer excellent opportunities for the growth of this technology.
Typical Freeze Application – Shaft Construction

Ground Freezing Assembling Freeze Pipes 1. Assembling freeze pipes.
Installation of freeze pipes 2. Installation of freeze pipes.
Application of freeze 3. Application of freeze with our electronically controlled refrigeration plant.
Frost development on freeze pipe headers 4. Frost development on freeze pipe headers.
Excavation following completion of freeze wall 5. Excavation following completion of freeze wall.
Construction of concrete liner 6. Construction of concrete liner. Once completed, refrigeration can be shut down.
Opening the portal revealing freeze pipes 7. Opening the portal revealing freeze pipes to be cut and capped prior to tunnel construction.

Appendix A

TABLE 2
SUMMARY OF METALS - TOXICITY CHARACTERISTIC LEACHING PROCEDURE
  Parameters Units Boring 1 Boring 1 Boring 2 Boring 2 Boring 3 Boring 3 Boring 4 Boring 5 Boring 5
S-1 S-2 S-1 S-2 S-1 S-2 S-1 S-1 S-2
  Depth Ft 9.5 19.0 20.0 40.0 20.0 30.0 20.0 16.0 26.0
  Material -- Sludge Silty Clay Sludge Silty Clay Sludge Silty Clay Sludge Silty Clay Sludge
  Arsenic ag/kg
(ppm)
< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 0.14 0.09
  Barium 0.55 0.14 0.13 0.57 0.75 1.08 0.52 0.47 1.30
  Cadmium < 0.01 < 0.01 0.02 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0\.01
  Chromium < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < .1 < .1
  Copper 10.4 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < .31
  Lead 0.56 0.93 0.80 < 0.15 9.21 < 0.15 < 0.15 < 0.1 < .1
  Mercury < 0.0002 < 0.0002 < 0.0002 < 0.0002 < 0.0002 < 0.0002 < 0.0002 < 0.0002 < .0002
  Nickel < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.1 < 0.5
  Selenium < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.02 < 0.1
  Silver < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02
  Zinc 3.65 3.28 3.29 0.39 15.2 0.32 0.11 0.10 4.30
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